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微波遥感 7

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LiFePO/C cathode materials synthesized by co-precipitation and microwave heating

XU Yunlong, TAO Lili, MA Hongyan, HUANG Huaqing

《化学科学与工程前沿(英文)》 2008年 第2卷 第4期   页码 422-427 doi: 10.1007/s11705-008-0082-4

摘要: LiFePO/C cathode materials were synthesized by a combination of co-precipitation and microwave heating using polyethylene glycol (PEG) as a carbon resource and the influence of microwave heating time on the structure and electrochemical performance of the materials was also discussed. The samples were characterized by X-ray diffraction (XRD), TEM, particle-size analysis and constant current charge-discharge experiment. The results show that the LiFePO/C heated for 9 min has a pure olive-type phase and excellent electrochemical performance. The initial discharge capacities of this sample are 154.3, 139.7, 123.9 mAh/g at the rates 0.1C, 0.2C, 1C at room temperature, respectively, and after 20 cycles remain 152.3, 134.3, 118.5 mAh/g, respectively.

关键词: polyethylene     electrochemical performance     combination     co-precipitation     diffraction    

Synthesis of boron modified CoMo/Al

Hui Shang, Chong Guo, Pengfei Ye, Wenhui Zhang

《化学科学与工程前沿(英文)》 2021年 第15卷 第5期   页码 1088-1098 doi: 10.1007/s11705-020-1969-y

摘要: Catalytic hydrodesulfurization (HDS) technique is widely used for clean gasoline production. However, traditional HDS catalyst (CoMo/ -Al O ) exhibits high hydrogenation performance of olefins (HYDO), resulting in the loss of gasoline octane number. To achieve high HDS/HYDO ratio, the key issue is to reduce the interaction between active metals and the support, therefore, in this research, the modified CoMo/ -Al O catalysts with various boron amounts were investigated under traditional or microwave heating. The effects of preparing methods as well as boron amounts on the active phase, acidic properties and HDS catalytic activities were examined. Results show that the modification, especially under microwave treatment, can significantly weaken the interaction between the active component and the support by enlarging the surface area and pore diameter, and reducing the acidity of the support. As a result, the stacking numbers of MoS slabs were obviously improved by the modification and microwave treatment, contributing to higher edge/rim ratio, and resulting in higher HDS performance and selectivity to olefin.

关键词: CoMo catalyst     boron modification     surface acidity     microwave heating     selective hydrodesulfurization    

微波熔炼在锡粉回收中的工业应用 Article

许磊, 彭金辉, 白海龙, Srinivasakannan C., 张利波, 吴庆田, 韩朝晖, 郭胜惠, 巨少华, 杨黎

《工程(英文)》 2017年 第3卷 第3期   页码 423-427 doi: 10.1016/J.ENG.2017.03.006

摘要:

本文探讨了微波加热在工业锡粉熔化中的应用。对离心雾化法制备的金属锡粉的形貌和粒径进行了表征锡粉颗粒均且呈球形,90% 的颗粒粒径为38~75 μm。过介电性能测试,研究了锡粉的微波吸收特性微波的穿作用对锡粉具有良好的整体加热能。温度高于150℃时,微波加热锡粉的主要机制是电导损耗设计开发了20 kW 微波熔炼锡合金装备,并将其应用于产业化该装备的加热率与常规方法相比能提高10 倍以上,缩短了熔炼工艺研究结果表明,微波加热加快了升温率,缩短了熔炼时间,锡回收率为97.79%,渣量仅为1.65%,其他损失低于0.56%;单位能耗仅为0.17 kW·h·kg−1远低于传统方法所要的能量。因此微波冶炼提高了加热效率,降低了能耗。

关键词: 微波加热     熔炼     锡粉     微波装备     回收    

A state-of-the-art review of solar passive building system for heating or cooling purpose

Arun Kumar NANDA,C K PANIGRAHI

《能源前沿(英文)》 2016年 第10卷 第3期   页码 347-354 doi: 10.1007/s11708-016-0403-0

摘要: The major portion of energy in a building is consumed by heating, ventilating, and air-conditioning (HVAC). The traditional heating and cooling systems contribute greatly to the emission of greenhouse gases, especially carbon dioxide. Four different ways, i.e., Trombe wall, solar chimney, unglazed transpired solar façade, and solar roof, are adopted for solar heating. Similarly, two major ways, i.e., evaporative cooling and building integrated evaporative cooling are adopted for cooling of the building. Therefore, an attempt has been made in this paper to compile the developments of solar heating and cooling technologies in a building.

关键词: HVAC     heating     cooling     solar heating     carbon dioxide (CO2) emissions    

A district heating system based on absorption heat exchange with CHP systems

Lin FU, Yan LI, Yi JIANG, Shigang ZHANG,

《能源前沿(英文)》 2010年 第4卷 第1期   页码 77-83 doi: 10.1007/s11708-010-0022-0

摘要: In order to decrease the energy consumption of large-scale district heating systems with cogeneration, a district heating system is presented in this paper based on absorption heat exchange in the cogeneration system named Co-ah cycle, which means that the cogeneration system is based on absorption heat exchange. In substations of the heating system, the temperature of return water of primary heat network is reduced to about 25°C through the absorption heat-exchange units. In the thermal station of the cogeneration plant, return water is heated orderly by the exhaust steam in the condenser, the absorption heat pumps, and the peak load heater. Compared with traditional heating systems, this system runs with a greater circuit temperature drop so that the delivery capacity of the heat network increases dramatically. Moreover, by recovering the exhausted heat from the condensers, the capacity of the district heating system and the energy efficiency of the combined heat and power system (CHP system) are highly developed. Therefore, high energy and economic efficiency can be obtained.

关键词: cogeneration     district heating     absorption heat exchange     Co-ah cycle    

钢坯加热的数值模拟

陈冠军

《中国工程科学》 2010年 第12卷 第2期   页码 57-61

摘要:

借助CFD仿真手段,模拟蓄热式加热炉内钢坯加热的实际状况,研究了钢坯长度、宽度方向上下表面和中心温度的温度分布,提出钢坯存在上下温差、四角边缘温度高和靠近出钢口钢坯温度低等问题。同时,研究了炉内不同厚度钢坯与加热时间的基本关系,比较了仿真计算结果与实际炉内加热时间,通过数值拟合,得出钢坯厚度与加热时间的拟合公式,可在生产实际中使用。上述研究结果可为加热炉钢坯加热制度的制定和优化提供依据。

关键词: 加热炉     钢坯     加热     模拟    

Impact of climate change on building heating energy consumption in Tianjin

Cao XIANG, Zhe TIAN

《能源前沿(英文)》 2013年 第7卷 第4期   页码 518-524 doi: 10.1007/s11708-013-0261-y

摘要: This paper investigated the variation of building heating energy consumption caused by global warming in Tianjin, China. Based on the hourly historical and monthly projected future (B1/A1B emissions scenarios) meteorological data, the variation of those relevant meteorological parameters was first analyzed. A TRNSYS simulation model for a reference building was introduced to investigate historical variation of office building energy consumption. The results showed that the 10-year-average heating energy consumption of 2001–2010 had reduced by 16.1% compared to that of 1961–1970. By conducting principal component analysis and regression analysis, future variation of building heating load was studied. For B1/A1B emissions scenarios, the multi-year-average heating load was found to decrease by 9.7% (18.1%)/10.2% (22.7%) compared to that of 1971–2010 by 2011–2050 (2051–2100).

关键词: global warming     office building     heating energy consumption    

Energy efficiency and carbon dioxide emissions reduction opportunities in district heating source in

Gaofeng CHEN, Xuejing ZHENG, Lin CONG

《能源前沿(英文)》 2012年 第6卷 第3期   页码 285-295 doi: 10.1007/s11708-012-0197-7

摘要: Building a trading market can promote energy conservation provided that the trading method is determined. Energy consumption for heat supply is huge. Tianjin Municipal Government is planning to establish an energy efficiency trading platform for district heating taking into consideration the experience in carbon trading market and specific situation in Tianjin. This paper presented an in-depth analysis of the district heating industry in Tianjin municipality, and identified the potentials of energy saving and carbon dioxide emissions reduction. Since energy efficiency was closely related to different heating source technologies, baselines were determined for boiler plants and thermal power plants respectively. Three scenarios were discussed for baseline determination. 472 boiler plants were surveyed and operational data relating to energy consumption were collected. Through data analysis, 27 boiler plants which have reasonable recorded energy consumption values were chosen as samples. By analyzing the dataset and referring to the related standards, method of determining the baseline for district heating carbon market was established. Finxally, the baseline for boiler plant was determined to be 52.0 kgce/GJ, and that for thermal power plant was 43.0 kgce/GJ in 2011. Carbon abatement against the baselines above was calculated and considerable carbon dioxide emissions reduction could be achieved.

关键词: district heating     energy efficiency     baseline     carbon abatement    

Higher heating value prediction of torrefaction char produced from non-woody biomass

Nitipong SOPONPONGPIPAT,Dussadeeporn SITTIKUL,Unchana SAE-UENG

《能源前沿(英文)》 2015年 第9卷 第4期   页码 461-471 doi: 10.1007/s11708-015-0377-3

摘要: The higher heating value of five types of non-woody biomass and their torrefaction char was predicted and compared with the experimental data obtained in this paper. The correlation proposed in this paper and the ones suggested by previous researches were used for prediction. For prediction using proximate analysis data, the mass fraction of fixed carbon and volatile matter had a strong effect on the higher heating value prediction of torrefaction char of non-woody biomass. The high ash fraction found in torrefied char resulted in a decrease in prediction accuracy. However, the prediction could be improved by taking into account the effect of ash fraction. The correlation developed in this paper gave a better prediction than the ones suggested by previous researches, and had an absolute average error (AAE) of 2.74% and an absolute bias error (ABE) of 0.52%. For prediction using elemental analysis data, the mass fraction of carbon, hydrogen, and oxygen had a strong effect on the higher heating value, while no relationship between the higher heating value and mass fractions of nitrogen and sulfur was discovered. The best correlation gave an AAE of 2.28% and an ABE of 1.36%.

关键词: higher heating value     correlation     biomass     proximate analysis     ultimate analysis    

Operating characteristic analysis on the ultra-thin low temperature floor-heating system

Hualing ZHANG, Xiaopeng SONG

《结构与土木工程前沿(英文)》 2013年 第7卷 第2期   页码 127-132 doi: 10.1007/s11709-013-0200-3

摘要: Prefabricated ultra-thin radiant heating panel, as a new heating terminal type, is becoming a highlight in Yangtze River Valley area, China recently. However, there is a lack of operating characteristic research in this region, especially the energy consumption and operating mode are even less. To obtain these data, a heating system was set up in a duplex house in Chongqing. The test results show that the floor heating system could almost satisfy thermal comfort requirement at supply water temperature 45°C. But the preheating time was up to 4.5 h which was 1 h longer than that at supply water temperature 50°C. Meanwhile, the energy consumption at supply water temperature 50°C increased 0.10 Nm /h, and the operating efficiency decrease about 2.6% compared to those at water temperature 45°C. Considering both the thermal lag and operating efficiency, a reasonable suggestion was proposed in this paper. That was, the standard families which just stay home at night should adopt the interim mode of partial room with part time. And the supply water temperature should be properly raised during the preheating period and lowered down in the steady heating stage.

关键词: ultra-thin floor heating panel     the preheating time     thermal comfort     energy saving    

Decomposition of perfluorooctanoic acid by microwave-activated persulfate: Effects of temperature, pH

Yuchi LEE, Shanglien LO, Jeff KUO, Chinghong HSIEH

《环境科学与工程前沿(英文)》 2012年 第6卷 第1期   页码 17-25 doi: 10.1007/s11783-011-0371-x

摘要: Microwave-hydrothermal treatment of persistent and bioaccumulative perfluorooctanoic acid (PFOA) in water with persulfate ( ) has been found effective. However, applications of this process to effectively remediate PFOA pollution require a better understanding on free-radical scavenging reactions that also take place. The objectives of this study were to investigate the effects of pH (pH= 2.5, 6.6, 8.8, and 10.5), chloride concentrations (0.01–0.15 mol·L ), and temperature (60°C, 90°C, and 130°C) on persulfate oxidation of PFOA under microwave irradiation. Maximum PFOA degradation occurred at pH 2.5, while little or no degradation at pH 10.5. Lowering system pH resulted in an increase in PFOA degradation rate. Both high pH and chloride concentrations would result in more scavenging of sulfate free radicals and slow down PFOA degradation. When chloride concentrations were less than 0.04 mol·L at 90°C and 0.06 mol·L at 60°C, presence of chloride ions had insignificant impacts on PFOA degradation. However, beyond these concentration levels, PFOA degradation rates reduced significantly with an increase in chloride concentrations, especially under the higher temperature.

关键词: microwave     perfluorooctanoic acid     pH     persulfate     chloride ions     perfluorocarboxylic acids    

Study on the microwave-assisted extraction of polyphenols from tea

Liyun WANG, Peiyong QIN, Yan HU,

《化学科学与工程前沿(英文)》 2010年 第4卷 第3期   页码 307-313 doi: 10.1007/s11705-009-0282-6

摘要: This study demonstrated a promising method for quickly extracting tea polyphenol (TP) by microwave-assisted extraction (MAE) technology. Some influential parameters, including MAE temperature, microwave power, concentration of extraction solvent, MAE time and the solid/liquid ratio, were investigated. The optimum condition of MAE was obtained by dual extraction with 60% ethanol (v/v) and the solid/liquid ratio 1:12 g/mL at 80°C for 10 minutes under the microwave power 600 W. The yield of TP was 96.5% under the described condition. Compared with traditional methods, including hot reflux extraction (HRE), ultrasound-assisted extraction (UAE) and supercritical fluid extraction (SFE), the extraction time was saved 8 times than that of HRE, and the yield was increased by 17.5%. The extraction time at comparable levels of production was saved 2 times, and the energy consumption was one fourth that of UAE. The extraction time was saved 5 times than that of SFE, and the yield of TP was increased by 40%. Moreover, compared with MAE of TP studied by others, it decreased the solid/liquid ratio from 1 ∶ 20 to 1 ∶ 12 g/mL without 90-min pre-leaching time, and the yield of TP was increased by 6%–40%.

关键词: energy consumption     microwave-assisted extraction     optimum condition     pre-leaching     concentration    

Characterisation of a microwave induced plasma torch for glass surface modification

Adam BENNETT, Nan YU, Fengzhou FANG, Marco CASTELLI, Guoda CHEN, Alessio BALLERI, Takuya URAYAMA

《机械工程前沿(英文)》 2021年 第16卷 第1期   页码 122-132 doi: 10.1007/s11465-020-0603-5

摘要: Microwave induced plasma torches find wide applications in material and chemical analysis. Investigation of a coaxial electrode microwave induced plasma (CE–MIP) torch is conducted in this study, making it available for glass surface modification and polishing. A dedicated nozzle is designed to inject secondary gases into the main plasma jet. This study details the adaptation of a characterisation process for CE–MIP technology. Microwave spectrum analysis is used to create a polar plot of the microwave energy being emitted from the coaxial electrode, where the microwave energy couples with the gas to generate the plasma jet. Optical emission spectroscopy analysis is also employed to create spatial maps of the photonic intensity distribution within the plasma jet when different additional gases are injected into it. The CE–MIP torch is experimentally tested for surface energy modification on glass where it creates a super-hydrophilic surface.

关键词: microwave induced plasma     spectrum analysis     surface modification    

Optimization model analysis of centralized groundwater source heat pump system in heating season

Shilei LU,Yunfang QI,Zhe CAI,Yiran LI

《能源前沿(英文)》 2015年 第9卷 第3期   页码 343-361 doi: 10.1007/s11708-015-0372-8

摘要: The ground-water heat-pump system (GWHP) provides a high efficient way for heating and cooling while consuming a little electrical energy. Due to the lack of scientific guidance for operating control strategy, the coefficient of performance (COP) of the system and units are still very low. In this paper, the running strategy of GWHP was studied. First, the groundwater thermal transfer calculation under slow heat transfixion and transient heat transfixion was established by calculating the heat transfer simulation software Flow Heat and using correction factor. Next, heating parameters were calculated based on the building heat load and the terminal equipment characteristic equation. Then, the energy consumption calculation model for units and pumps were established, based on which the optimization method and constraints were established. Finally, a field test on a GWHP system in Beijing was conducted and the model was applied. The new system operation optimization idea for taking every part of the GWHP into account that put forward in this paper has an important guiding significance to the actual operation of underground water source heat pump.

关键词: optimization model     groundwater source heat pump system     theoretical analysis     example verification     heating season    

Fault simulation of boiler heating surface ash deposition in a power plant system

Weiwei ZHANG, Huisheng ZHANG, Ming SU

《能源前沿(英文)》 2011年 第5卷 第4期   页码 435-443 doi: 10.1007/s11708-011-0162-x

摘要: The simulation model of a power generation system was developed based on EASY5 simulation platform. The performances of the power plant under the conditions of the furnace slagging and ash deposition of the heating surfaces in the boiler were simulated. The results show that the simulation model can reasonably reflect the characteristics of the power plant when each component is under fault conditions. Through fault simulation, the change of the performance parameters can be obtained, which can be used in fault diagnosis system as the diagnosis criterion for expert system.

关键词: boiler     slagging     ash deposition     fault simulation    

标题 作者 时间 类型 操作

LiFePO/C cathode materials synthesized by co-precipitation and microwave heating

XU Yunlong, TAO Lili, MA Hongyan, HUANG Huaqing

期刊论文

Synthesis of boron modified CoMo/Al

Hui Shang, Chong Guo, Pengfei Ye, Wenhui Zhang

期刊论文

微波熔炼在锡粉回收中的工业应用

许磊, 彭金辉, 白海龙, Srinivasakannan C., 张利波, 吴庆田, 韩朝晖, 郭胜惠, 巨少华, 杨黎

期刊论文

A state-of-the-art review of solar passive building system for heating or cooling purpose

Arun Kumar NANDA,C K PANIGRAHI

期刊论文

A district heating system based on absorption heat exchange with CHP systems

Lin FU, Yan LI, Yi JIANG, Shigang ZHANG,

期刊论文

钢坯加热的数值模拟

陈冠军

期刊论文

Impact of climate change on building heating energy consumption in Tianjin

Cao XIANG, Zhe TIAN

期刊论文

Energy efficiency and carbon dioxide emissions reduction opportunities in district heating source in

Gaofeng CHEN, Xuejing ZHENG, Lin CONG

期刊论文

Higher heating value prediction of torrefaction char produced from non-woody biomass

Nitipong SOPONPONGPIPAT,Dussadeeporn SITTIKUL,Unchana SAE-UENG

期刊论文

Operating characteristic analysis on the ultra-thin low temperature floor-heating system

Hualing ZHANG, Xiaopeng SONG

期刊论文

Decomposition of perfluorooctanoic acid by microwave-activated persulfate: Effects of temperature, pH

Yuchi LEE, Shanglien LO, Jeff KUO, Chinghong HSIEH

期刊论文

Study on the microwave-assisted extraction of polyphenols from tea

Liyun WANG, Peiyong QIN, Yan HU,

期刊论文

Characterisation of a microwave induced plasma torch for glass surface modification

Adam BENNETT, Nan YU, Fengzhou FANG, Marco CASTELLI, Guoda CHEN, Alessio BALLERI, Takuya URAYAMA

期刊论文

Optimization model analysis of centralized groundwater source heat pump system in heating season

Shilei LU,Yunfang QI,Zhe CAI,Yiran LI

期刊论文

Fault simulation of boiler heating surface ash deposition in a power plant system

Weiwei ZHANG, Huisheng ZHANG, Ming SU

期刊论文